Publications

28. Divergent Reactivity of a Cobalt Complex with CF3 versus CH3 Electrophiles

Kuruppu, S.; Zou, M.; Waldie, K. M. In Review.

27. Morphology Variations of Transition Metal Oxides for the Oxygen Evolution Reaction

Teeluck, K.; Waldie, K. M. In Revision.

26. Nanospike Nickel-Iron Oxalate as an Efficient Electrocatalyst for the Oxygen Evolution Reaction

Teeluck, K. M.; Carignan, G. M.; Dogan, M.; Waldie K. M. In Revision.

Preprint posted on ChemRxiv. DOI: 10.26434/chemrxiv-2024-2rpfc

25. Electrocatalytic Formate Oxidation by Cobalt-Phosphine Complexes

Katipamula, S.; Cook, A. W.; Niedzwiecki, I.; Nadeesha, C.; Parihar, A.; Emge, T. J.; Waldie, K. W. ACS Catal. 2025, 15, 1771-1781. DOI: 10.1021/acscatal.4c03189

Preprint posted on ChemRxiv. DOI: 10.26434/chemrxiv-2023-tfn6t

24. Hydricity as a Guide in H2 Evolution, Formic Acid Decomposition, and Transfer Hydrogenation: A Case Study with Ir(Cp*)(2-phenylpyridine)H

Miller, C. J.; Weddle, L. R.; Okuno, S.; Brunner, F. M.; Lee, B; Waldie, K. M.; Kubiak, C. P. Organometallics, 2024, 43, 3258-3264. DOI: 10.1021/acs.organomet.4c00301

23. Oxidation-Induced Ligand Swap: Oxygen Insertion into a Cobalt-Phosphine Complex

Katipamula, S.; Nadeesha, C.; Emge, T. J.; Waldie, K. M. Organometallics, 2024, 43, 2036-2043. DOI: 10.1021/acs.organomet.4c00254

Preprint posted on ChemRxiv. DOI: 10.26434/chemrxiv-2024-r59wp

22. Redox-Active Ligand Promoted Multielectron Reactivity at Earth-Abundant Transition Metal Complexes

Zou, M.; Waldie, K. M. Inorg. Chem. Front. 2024, 11, 5795-5809. DOI: 10.1039/D4QI01265H

21. Metal- versus Ligand-Centered Reactivity of a Cobalt-Phenylenediamide Complex with Electrophiles

Zou, M.; Kuruppu, S.; Emge, T. J.; Waldie, K. M. Dalton Trans. 2024, 53, 13174-13183. DOI: 10.1039/D4DT01655F

Preprint posted on ChemRxiv. DOI: 10.26434/chemrxiv-2024-45wll-v2

20. Electrocatalytic Formate and Alcohol Oxidation by Hydride Transfer at First-Row Metal Complexes

White, N. M.; Waldie, K. M. Dalton Trans. 2024, 53, 11644-11654. DOI: 10.1039/D3DT04304E

19. Redox-Active Ligand Promoted Electrophile Addition at Cobalt

Zou, M.; Waldie, K. W. Chem. Commun. 2023, 59, 14693-14696. DOI: 10.1039/D3CC04869A

Invited article as part of the 2023 Emerging Investigators Special Collection.

18. Metal–Ligand Proton Tautomerism, Electron Transfer, and C(sp3)–H Activation by a 4-Pyridinyl-Pincer Iridium Hydride Complex

Bhatti, T. M.; Kumar, A.; Parihar, A.; Moncy, H. K.; Emge, T. J.; Waldie, K. M.; Hasanayn, F.; Goldman, A. S. J. Am. Chem. Soc. 2023, 145, 18296-18306. DOI: 10.1021/jacs.3c03376

17. Two-Electron Redox Tuning of Cyclopentadienyl Cobalt Complexes Enabled by the Phenylenediamide Ligand

Zou, M.; Emge, T. J.; Waldie, K. M. Inorg. Chem. 2023, 62, 10397-10407. DOI: 10.1021/acs.inorgchem.3c01283

Previous version deposited on ChemRxiv. DOI: 10.26434/chemrxiv-2023-l58hm

16. Controlled-Potential Electrolysis for Evaluating Molecular Electrocatalysts

Katipamula, S.; White, N. M.; Waldie, K. M. Chem Catal. 2023, 3, 100561. DOI: 10.1016/j.checat.2023.100561

Invited article as part of the Women in Catalysis Special Issue.

15. Design of a Minimal di-Nickel Hydrogenase Peptide

Mancini, J. A.; Pike, D. H.; Poudel, S.; Timm, J.; Tyryshkin, A. M.; Siess, J.; Molinaro, P.; McCann, J. J.; Waldie, K. M.; Koder, R. L.; Falkowski, P. G.; Nanda, V. Sci. Adv. 2023, 9, eabq1990. DOI: 10.1126/sciadv.abq1990

14. Recent Progress in the Development of Molecular Electrocatalysts for Formate Oxidation

Waldie, K. M.; Katipamula, S. Catalysis Research 2022, 2, 15. DOI: 10.21926/cr.2201006

13. Insights into Formate Oxidation by a Series of Cobalt Piano-Stool Complexes Supported by Bis(phosphino)amine Ligands

Cook, A. W.; Emge, T. J.; Waldie, K. M. Inorg. Chem. 2021, 60, 7372-7380. DOI: 10.1021/acs.inorgchem.1c00563

12. Molecular Electrocatalysts for Alcohol Oxidation: Insights and Challenges for Catalyst Design

Cook, A. W.; Waldie, K. M. ACS Appl. Energy Mater. 2020, 3, 38-46. DOI: 10.1021/acsaem.9b01820

Invited article as part of the Young Investigator Forum Special Issue.

Prior Publications

11. Approaches to Controlling Homogeneous Electrochemical Reduction of Carbon Dioxide

Barrett, J. A.; Brunner, F. M.; Cheung, P. L.; Kubiak, C. P.; Lee, G. L.; Miller, C. J.; Waldie, K. M.; Zhanaidarova, A. In Carbon Dioxide Electrochemistry: Homogeneous and Heterogeneous Catalysis; Robert, M.; Costentin, C.; Daasbjerg, K., Eds.; Energy and Environment Series No. 28; Royal Society of Chemistry, 2021; pp 1-66. DOI: 10.1039/9781788015844-00001

10. Utilization of Thermodynamic Scaling Relationships in Hydricity to Develop Nickel HER Electrocatalysts with Weak Acids and Low Overpotentials

Ostericher, A. L.; Waldie, K. M.; Kubiak, C. P. ACS Catal. 2018, 8, 9596-9603. DOI: 10.1021/acscatal.8b02922

9. Protonation of a Cobalt Phenylazopyridine Complex at the Ligand Yields a Proton, Hydride, and Hydrogen Atom Transfer Reagent

McLoughlin, E.; Waldie, K. M.; Ramakrishnan, S.; Waymouth, R. M. J. Am. Chem. Soc. 2018, 140, 13233-13241. DOI: 10.1021/jacs.8b06156

8. Transition-Metal Hydride Catalysts for Sustainable Interconversion of CO2 and Formate: Thermodynamic and Mechanistic Considerations

Waldie, K. M.; Brunner, F. M.; Kubiak, C. P. ACS Sustainable Chem. Eng. 2018, 6, 6841-6848. DOI: 10.1021/acssuschemeng.8b00628

7. Hydricity of Transition Metal Hydrides: Thermodynamic Conditions for CO2 Reduction

Waldie, K. M.; Ostericher, A. L.; Reineke, M. H.; Sasayama, A. F.; Kubiak, C. P. ACS Catal. 2018, 8, 1313-1324. DOI: 10.1021/acscatal.7b03396

6. Cyclopentadienyl Cobalt Complexes as Precatalysts for Electrocatalytic Hydrogen Evolution

Waldie, K. M.; Kim, S.-K.; Ingram, A. J.; Waymouth, R. M. Eur. J. Inorg. Chem. 2017, 2755-2761. DOI: 10.1002/ejic.201700188

5. Multielectron Transfer at Cobalt: Influence of the Phenylazopyridine Ligand

Waldie, K. M.; Ramakrishnan, S.; Kim, S.-K.; Maclaren, J. K.; Chidsey, C. E. D.; Waymouth, R. M. J. Am. Chem. Soc. 2017, 139, 4540-4550. DOI: 10.1021/jacs.7b01047

4. Electrocatalytic Alcohol Oxidation with Ruthenium Transfer Hydrogenation Catalysts

Waldie, K. M.; Flajslik, K. R.; McLoughlin, E.; Chidsey, C. E. D.; Waymouth, R. M. J. Am. Chem. Soc. 2017, 139, 738-748. DOI: 10.1021/jacs.6b09705

3. Experimental and Theoretical Study of CO2 Insertion into Ruthenium Hydride Complexes

Ramakrishnan, S.; Waldie, K. M., Warnke, I.; De Crisci, A. G.; Batista, V. S.; Waymouth, R. M.; Chidsey, C. E. D. Inorg. Chem. 2016, 55, 1623-1632. DOI: 10.1021/acs.inorgchem.5b02556

2. Redox-Active Bridging Ligands based on Indigo Diimine ("Nindigo") Derivatives

Nawn, G.; Waldie, K. M.; Oakley, S. R.; Peters, B. D.; Mandel, D.; Patrick, B. O.; McDonald, R.; Hicks, R. G. Inorg. Chem. 2011, 50, 9826-9837. DOI: 10.1021/ic200388y

1. “Nindigo”: Synthesis, Coordination Chemistry, and Properties of Indigo Diimines as a New Class of Functional Bridging Ligands

Oakley, S. R.; Nawn, G.; Waldie, K. M.; MacInnis, T. D.; Patrick, B. O.; Hicks, R. G. Chem. Comm. 2010, 46, 6753-6755. DOI: 10.1039/C0CC01736A